Case study of landfill reclamation at a Florida landfill site

A landfill reclamation project was considered to recover landfill airspace and soil, reduce future groundwater impacts by removing the waste buried in the unlined area, and optimize airspace use at the site. A phased approach was utilized to evaluate the technical and economic feasibility of the reclamation project; based on the results of these evaluations, approximately 6.8 ha of the unlined cells were reclaimed. Approximately 371,000 in-place cubic meters of waste was mined from 6.8 ha in this project. Approximately 230,600 cubic meters of net airspace was recovered due to beneficial use of the recovered final cover soil and reclaimed soil as intermediate and daily cover soil, respectively, for the current landfill operations. This paper presents the researchers’ landfill reclamation project experience, including a summary of activities pertaining to reclamation operations, an estimation of reclamation rates achieved during the project, project costs and benefits, and estimated composition of the reclaimed materials.     

Forecasting volatility of carbon under EU ETS: a multi-phase study

Environmental Economics and Policy Studies - Carbon management is a strategic priority and organizations need to forecast carbon for that. We aim to find out the best ARIMA-GARCH model for...     

Bacterial assisted phytoremediation for enhanced degradation of highly sulfonated diazo reactive dye

Purpose

Phytoremediation is the exploitation of plants and their rhizospheric microorganisms for pollutants treatment like textile dyes, which are toxic, carcinogenic and mutagenic from the effluent. The purpose of this work was to explore a naturally found plant and bacterial synergism to achieve an enhanced degradation of Remazol Black B dye (RBB).

Methods

In vitro cultures of Zinnia angustifolia were obtained by seed culture method. Enzymatic analysis of the plant roots and Exiguobacterium aestuarii strain ZaK cells was performed before and after decolorization of RBB. Metabolites of RBB formed after its degradation were analyzed using UV?CVis spectroscopy, high-performance liquid chromatography (HPLC), Fourier transform infrared (FTIR) and gas chromatography?Cmass spectrometry (GC-MS). Phytotoxicity studies were performed.

Results

The consortium ZE was found to be more efficient than individual plant and bacteria. Z. angustifolia roots showed significant induction in the activities of lignin peroxidase, laccase, DCIP reductase and tyrosinase during dye decolorization. E. aestuarii showed significant induction in the activities of veratryl alcohol oxidase, azo reductase and DCIP reductase. Analysis of metabolites revealed differential metabolism of RBB by plant, bacteria and consortium ZE. E. aestuarii and Z. angustifolia led to the formation of 3,6-diamino-4-hydroxynaphthalene-2-sulfonic acid, (ethylsulfonyl)benzene, and 3,4,6-trihydroxynaphthalene-2-sulfonic acid and propane-1-sulfonic acid, respectively, whereas consortium ZE produced 4-hydroxynaphthalene-2-sulfonic acid, naphthalene-2-sulfonic acid and 4-(methylsulfonyl)phenol. The phytotoxicity study revealed the nontoxic nature of the metabolites formed after dye degradation.

Conclusion

Consortium ZE was found to be more efficient and faster in the degradation of RBB when compared to degradation by Z. angustifoila and E. aestuarii individually.     

Release kinetics of β-cyfluthrin from its encapsulated formulations in water

Controlled release formulations of β-cyfluthrin, a non-systemic, broad spectrum contact insecticide, have been prepared using laboratory synthesized poly(ethylene glycol) (PEG) based amphiphilic copolymers. Copolymers of polyethylene glycols of different molecular weights and various dimethyl esters, viz. dimethyl isophthalate, which self assemble into nano micellar aggregates in aqueous media, have been synthesized. The kinetics of β-cyfluthrin from developed controlled release (CR) formulations were studied in comparison with that of the commercially available 025 SC. Release from the commercial formulation was faster than with the developed CR formulations. The rate of release of encapsulated β-cyfluthrin from nano micellar aggregates is reduced by increasing the molecular weight of PEG. The diffusion exponent (n value) of β-cyfluthrin in water ranged from 0.427 to 0.622 in the tested formulations. The release was diffusion controlled with a half-release time (t(?)) of 3.92 to 7.9 days in water from different formulations, and the period of optimum availability (POA) of β-cyfluthrin ranged from 1.4 to 20.5 days. The results suggest that the application rate of β-cyfluthrin can be optimized to achieve insect control at the desired level and period.     

Field evaluation of resistivity sensors for in situ moisture measurement in a bioreactor landfill

The ability of resistance-based sensors to measure in situ waste moisture content in a landfill was examined. One hundred and thirty-five resistance-based sensors were installed in a leachate recirculation well field at a bioreactor landfill in Florida, US. The performance of these sensors was studied for a period of over 6 years. The sensors were found to respond to an increase in moisture resulting from leachate recirculation. It was observed that 78% of sensors worked successfully in the field during the study period. The initial spatial average moisture content determined by the sensor readings (using a laboratory-derived calibration) was 42.8% compared to 23% from gravimetric readings. Eighteen sensors (13%) showed that they were saturated before liquid addition, and no change in moisture content was observed in these sensors during the study period. Laboratory-derived calibration methods resulted in an over-estimation of moisture content. An alternate field-calibration method, where wetted sensor output was assumed equal to the average of gravimetric measurements for wet samples, was evaluated. The final spatial average moisture contents were 64.2% and 44.4% for the laboratory-derived and field-derived calibration methodologies, respectively, compared to 45% measured gravimetrically from excavated waste samples. When moisture content was determined using a mass balance approach, the result was 34.6%. The results suggest that when appropriately calibrated, resistivity-based sensors can be used to obtain a reasonably accurate estimate of local moisture content. However, caution should be taken to extend the moisture content values that are representative of waste surrounding the sensors to estimate the overall moisture content on the landfill-wide scale.     

Phytoremediation of textile effluent and mixture of structurally different dyes by Glandularia pulchella (Sweet) Tronc

Plants of Glandularia pulchella (Sweet) Tronc. performed decolorization of structurally different dyes to varying extent because of induction of different set of enzymes in response to specific dyes. Differential pattern of enzyme induction with respect to time was obtained for lignin peroxidase, veratryl alcohol oxidase, tyrosinase and dichlorophenolindophenol reductase during the decolorization of dye mixture, whose combined action resulted in greater and faster decolorization of dyes. HPLC, FTIR and High Performance Thin Layer Chromatography (HPTLC) analysis confirmed degradation of dyes from textile effluent and mixture. HPTLC demonstrated progressive decolorization of dye mixture along with preferential degradation of the dyes. G. pulchella showed reduction in American Dye Manufacturer's Institute from 405 to 21 and 418 to 22, in case of textile effluent and mixture of dyes respectively. The non-toxic nature of the metabolites of degraded textile dye effluent and mixture of dyes was revealed by phytotoxicity studies.     

When apologizing hurts: Felt transgression and restoration efforts

Apologizing is important for conflict resolution and relationship reconciliation, yet apologies often fail to restore the damaged relationship. While much research has been devoted to investigating the victims' reactions upon receiving an apology, in this paper, we adopt an apologizer-centric approach and explore the phenomenon of apologizing with no felt transgression (vis-à-vis when there is felt transgression) along with its affective and reconciliation outcomes for the apologizer. Based on Appraisal Tendency Framework, we predict that apologizing with no felt transgression will lead to reduced guilt and increased anger in the apologizer, which will result in a decreased level of their restoration efforts towards the victim. In addition, we further hypothesize about the role of organizational conflict cultures in influencing the relationship between apologizing and restoration efforts via guilt and anger. Study 1 uses a micro-narrative procedure and an inductive data analysis approach to demonstrate the varied situations and motivations of employees apologizing with (no) felt transgression, Study 2 utilizes an experimental design to examine the mediation effect, and Study 3 employs the critical incident technique to test our whole research model. Our hypotheses were largely supported across our studies. Theoretical and practical implications are discussed.     

Phytoremediation of a sulphonated azo dye Green HE4B by <Emphasis Type="Italic">Glandularia pulchella</Emphasis> (Sweet) Tronc. (Moss Verbena)

Purpose  

The dyes and dye stuffs present in effluents released from textile dyeing industries are potentially mutagenic and carcinogenic. Phytoremediation technology can be used for remediating sites contaminated with such textile dyeing effluents. The purpose of the work was to explore the potential of Glandularia pulchella (Sweet) Tronc. to decolorize different textile dyes, textile dyeing effluent, and synthetic mixture of dyes.     

Potentiality of different isolates of wilt fungus Fusarium oxysporum collected from rhizosphere of tomato against root-knot nematode Meloidogyne incognita

This investigation was undertaken to determine the effect of culture filtrates of different isolates of Fusarium oxysporum f. sp. lycopersici on mortality of Meloidogyne incognita juveniles and egg hatching. It was observed that different concentrations including standard extract (S.E), 1:10 and 1:100 dilutions of all fungal filtrates inhibited egg hatch when compared with control. Minimum mortality and maximum hatching was observed in BRT (showing least mortality) isolate of F. oxysporum, while maximum mortality and minimum egg hatching was recorded in BGT (showing maximum mortality) isolate. Larval mortality was decreased with a decrease in concentration and the least mortality was observed in 1:100 when compared with SE and 1:10. The potentiality of both the isolates (BRT and BGT) against root-knot nematode M. incognita was confirmed by the pathogenicity test on tomato. These observations confirmed that F. oxysporumisolates possesses variability in pathogenicity ranging from pathogenic to bio-control agent. The plants inoculated with BRT isolate failed to show wilt symptoms while plants inoculated with BGT isolate showed wilt indices.